According to close friends, the Duchess of Cambridge was not interested in Prince William in the beginning, when they were mere students. In fact at that point in time she was more smitten by a guy called Harry.
Wills and Kate as first year students at St. Andrews, 2002.
Even though later they fell madly in love with each other and married in April last year, apparently Duchess Kate, the former Kate Middleton wasn't bowled over by the dashing young British royal initially when she found out that they were to attend the same university, St. Andrews, in Scotland.
For all the juicy details on Kate Middleton student years and her crushes check the link below:
St. Andrews where Kate & Wills fell in love